Unlockable Characters:
Unlock the following characters by performing the corresponding tasks:

Play as Android Rachel – Beat Trial 29
Play as Charles The Third – Beat the second level of Story mode
Play as Devil Buster Dante – Beat the first level of Story mode (all four chapters)
Play as Director Blue – Beat Trial 1
Play as Fighter Bianky and Friends – Beat Trial 13
Play as Gran Bruce – Beat Trial 35
Play as Heroine Silvia – Beat Trial 37
Play as Hulk Davidson – Beat Trial 14
Play as Manager Jet – Beat Trial 19
Play as Movie Fan Joe – Beat Trial 5
Play as Stylish Alastor – Beat Trial 34
Play as Young Blue Jr. – Beat Trial 24
Play as Young Captain Blue – Beat Trial 40

Alternate costumes:
To unlock alternate costumes for every character, beat all 40 Trial mode missions. To change a character’s costume, highlight a character at the chracter selection screen, then press Square.

Special Story mode stages:
To unlock Special Story mode stages, collect the sixteen puzzle pieces in each stage in Story mode.

Art gallery:
To unlock the Art gallery, collect all sixteen puzzle pieces in each Special stage in Story mode.

Unlock the following movies by beating the corresponding Story mode chapters:

Atlantis: Four Adventures Of The Sea – Gulliver’s Battles
Atlantis: Four Adventures Of The Sea Special Edition – V-Puzzle 6
Boss*Boss*Bang*Bang: All previous chapters except The Hidden Hideout
Captain Blue Begins – Viewtiful Cartoon World
Captain Blue Begins Special Edition – V-Puzzle 3
Gulliver’s Battles – Truth Of The Black Film
Gulliver’s Battles Special Edition – V-Puzzle 5
Les Acteurs Incroyable: Atlantis – Four Adventures Of The Sea
Red Hot Rumble – Boss*Boss*Bang*Bang
Riddle Of The Incan Empire! Special Edition – V-Puzzle 1
The Hidden Hideout – Any chapter with Charles The Third, Hulk Davidson, and Gran Bruce
Truth Of The Black Film – Captain Blue Begins
Truth Of The Black Film Special Edition – V-Puzzle 4
Viewtiful Cartoon World – Riddle Of The Incan Empire!
Viewtiful Cartoon World Special Edition – V-Puzzle 2
Ending Movie – Les Acteurs Incroyable
Last Battle Intro Movie – Les Acteurs Incroyable
Opening Movie – Riddle Of The Incan Empire!